Adam (BtVS)/Sasshi (Magical Shopping Arcade Abenobashi)
Biff (Back to the Future)/Piper Halliwell (Charmed)
Buster (Mythbusters)/Gomez Adams
Captain Jack Sparrow (Pirates of the Caribbean)/The Cigarette-Smoking Man (X-Files)
Furura (Pokemon)/Baron Unterbheit (Venture Brothers)
Hal Sparks (I Love the 70s/80's/90's)/Michael (La Femme Nikita)
He-Man/Robin (Batman)
Jar Jar Binks (Star Wars)/Joan Girardi (Joan of Arcadia) (God sure loves to mess with her.)
Jordan Sullivan (Scrubs)/Guido Orefice (Life is Beautiful)
Lex Luthor/Sofia Curtis (CSI)
Mia Wallace (Pulp Fiction)/Beverly Crusher (Star Trek)
Mrs. Smith (Mr. and Mrs. Smith)/Mary Shelley
Queen Victoria/Johnny Smith (Dead Zone)
Richter Belmont (Castlevania: Symphony of the Night)/Friedman (Joan of Arcadia)
Rover (The Prisoner)/Pyro (X-Men movieverse)
Sherlock Holmes/Cassie (Buffy)
The Archdean (Illuminati University)/Taro Kagami (Death Note: Pilot)
The Bursar (Discworld)/God (Bible)
Tom Berensen (Animorphs)/The Devil (Brimstone)
Tony Rodriguez (NYPD Blue)/Gabe (Penny Arcade)
The very very scary thing about this list is how many of these work well if there's no romance involved.
Biff (Back to the Future)/Piper Halliwell (Charmed)
Buster (Mythbusters)/Gomez Adams
Captain Jack Sparrow (Pirates of the Caribbean)/The Cigarette-Smoking Man (X-Files)
Furura (Pokemon)/Baron Unterbheit (Venture Brothers)
Hal Sparks (I Love the 70s/80's/90's)/Michael (La Femme Nikita)
He-Man/Robin (Batman)
Jar Jar Binks (Star Wars)/Joan Girardi (Joan of Arcadia) (God sure loves to mess with her.)
Jordan Sullivan (Scrubs)/Guido Orefice (Life is Beautiful)
Lex Luthor/Sofia Curtis (CSI)
Mia Wallace (Pulp Fiction)/Beverly Crusher (Star Trek)
Mrs. Smith (Mr. and Mrs. Smith)/Mary Shelley
Queen Victoria/Johnny Smith (Dead Zone)
Richter Belmont (Castlevania: Symphony of the Night)/Friedman (Joan of Arcadia)
Rover (The Prisoner)/Pyro (X-Men movieverse)
Sherlock Holmes/Cassie (Buffy)
The Archdean (Illuminati University)/Taro Kagami (Death Note: Pilot)
The Bursar (Discworld)/God (Bible)
Tom Berensen (Animorphs)/The Devil (Brimstone)
Tony Rodriguez (NYPD Blue)/Gabe (Penny Arcade)
The very very scary thing about this list is how many of these work well if there's no romance involved.